INTERURBAN

 

dfg_gross
Soil Organic Matter and its water binding and its Influence on Water Repellency and Sorption in Urban Soils

INTERURBAN - HUMUS I &II,
DFG: SCHA 849/4-1,4-2,4-3 und 4-4
interurban
Interdisziplinäre DFG-Forschergruppe FOR 409 INTERURBAN. Systemverständnis: Wasser- und Soffdynamik urbaner Standorte

 

Summary

Phase I

The subproject HUMUS aimed to characterize the interaction between water and organic matter and to derive their effects on the sorption of hydrophobic organic pollutants

In this first phase the subproject HUMUS examined the binding of water in soil organic matter by thermoanalytic methods (in particular DSC). In addition, 1H NMR relaxation (subproject GEO) as well as kinetic studies of the release and swelling of soil organic matter were performed. Field experiments and microcosmic investigations of the research group were carried out in order to analyze the connection between the water binding in soil organic matter and other soil properties. The first phase has shown that besides the macromolecular properties of the organic matter, biofilms and the water repellency also represent important characteristics of a habitat.

Phase II

The subproject HUMUS aims to characterize the interaction between water and organic matter and to derive their effects on the sorption of hydrophobic organic pollutants. To understand the appearance of water repellency in its dynamics and spatial heterogeneity, the physical and chemical causalities are to be studied.

In collaboration with the subproject GEO, the 1H NMR relaxation will be used to investigate kinetics and mechanisms of wetting. In the second year there will be a focus on thermal and rheological properties of biofilms and their dependence on soil fauna, stress factors and xeno-(biotic) substances (subprojects MIKRO, FAUNA, KOLLOID and MOBIL).

Differential Scanning Calorimetry and Thermo-Mechanical analysis as well as rheological methods will be used to identify gel properties of biofilms. In the third year, the effects of water repellency and glass transition behavior on the sorption of an organic marker/pointer-pollutant will be examined. The results are to enter a model of the subproject SOIL.

Project Leaders

Prof. Dr. Gabriele E. Schaumann (Project leader)
Prof. Dr. Wolfgang Rotard (Co-Applicant)

 

Publications

with peer-review

2010

18. Diehl, Dörte, Bayer, Julia V., Woche, S.K., Bryant, R., Doerr, S.H., Schaumann, Gabriele E. 2010. Reaction of soil water repellency on artificially induced changes in soil pH. Geoderma. 158 (3-4): 375-384. Download

2009

17. Diehl, Dörte, Ellerbrock, Ruth H., Schaumann, Gabriele Ellen 2009. DRIFT-Spectroscopy of untreated and dried soil samples of different wettability. European Journal of Soil Science. 60 557-566. Download

2007

16. Hurraß, Julia, Schaumann, Gabriele Ellen 2007. Hydration kinetics of wettable and water repellent soil samples. Soil Science Society of America Journal. 71 (2): 280-288. Download

15. Hurraß, Julia, Schaumann, Gabriele E. 2007. Influence of the sample history and the moisture status on the thermal behavior of soil organic matter. Geochimica et Cosmochimica Acta. 71 691-702. Download

14. Bayer, Julia V., Schaumann, Gabriele E. 2007. Development of soil water repellency in the course of isothermal drying and upon pH changes in two urban soils. Hydrological Processes. 21 (17): 2266 - 2275. Download

13. Schaumann, Gabriele Ellen, Braun, Burga, Kirchner, Dörte, Rotard, Wolfgang, Szewzyk, Ulrich, Grohmann, Elisabeth 2007. Influence of biofilms on the water repellency of urban soil samples. Hydrological Processes. 21 (17): 2276 - 2284. Download

12. Diehl, Doerte, Schaumann, Gabriele E. 2007. The nature of wetting on urban soil samples: wetting kinetics and evaporation assessed from sessile drop shape. Hydrological Processes. 21 (17): 2255 - 2265. Download

2006

11. Hurraß, Julia, Schaumann, Gabriele E. 2006. Properties of soil organic matter and aqueous extracts of actually water repellent and wettable soil samples. Geoderma. 132 (1-2): 222-239. Download

10. Schaumann, Gabriele Ellen 2006. Soil organic matter beyond molecular structure. 2. Amorphous nature and physical aging. Journal of Plant Nutrition and Soil Science. 169 (2): 157-167. Download

9. Schaumann, Gabriele Ellen 2006. Soil organic matter beyond molecular structure. 1. Macromolecular and supramolecular characteristics. Journal of Plant Nutrition and Soil Science. 169 (2): 145-156. Download

2005

8. Hurrass, Julia, Schaumann, Gabriele E. 2005. Is glassiness a common characteristic of soil organic matter?. Environmental Science and Technology. 39 (24): 9534-9540. Download

7. Schaumann, Gabriele E., LeBoeuf, Eugene J., DeLapp, R. C., Hurraß, Julia 2005. Thermomechanical analysis of air-dried whole soil samples. Thermochimica Acta. 436 (1-2): 83-89. Download

6. Schaumann, Gabriele E., LeBoeuf, Eugene J. 2005. Glass transitions in peat - their relevance and the impact of water. Environmental Science and Technology. 39 (3): 800-806. Download

5. Schaumann, Gabriele E., Hobley, Eleanor, Hurraß, Julia, Rotard, Wolfgang 2005. H-NMR Relaxometry to monitor wetting and swelling kinetics in high organic matter soils. Plant and Soil. 275 (1-2): 1-20. Download

4. Schaumann, Gabriele E. 2005. Matrix relaxation and change of water state during hydration of peat. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 265 (1-3): 163-170. Download

2004

3. Schaumann, Gabriele E., Hurraß, Julia, Müller, Martin, Rotard, Wolfgang 2004. Swelling of organic matter in soil and peat samples: insights from proton relaxation, water absorption and PAH extraction. Ghabbour, E. A.; Davies, G. Humic Substances: Nature's Most Versatile Materials. New York: Taylor and Francis, Inc.. 101-117.

2001

2. Schaumann, Gabriele Ellen 2001. Kinetic Studies on the Dissolution of Soil Organic Matter. Swift, Roger S.; Spark, Kaye M. Understanding managing organic matter in soils, sediments waters. Adelaide, Australia: International Humic Substances Society. 83-89.

2000

1. Schaumann, Gabriele Ellen, Antelmann, Olivia 2000. Thermal characteristics of soil organic matter measured by DSC: A hint on a glass transition. Journal of Plant Nutrition and Soil Science. 163 (2): 179-181. Download

Other publications

2010

39. Diehl, Dörte, Schaumann, Gabriele E. 2010. Mechanisms controlling dynamics at the soil-water interface. Gilkes, R.J.; Prakongkep, N. 19th World Congress of Soil Science (WCSS). Brisbane, Australien: IUSS. Symposium 2.2.1: Biogeochemical interfaces in soil 145-148.

2006

38. Schaumann, Gabriele Ellen 2006. Die organische Bodensubstanz als amorphe Matrix - Alterung, Quellung und Benetzung im Wechselspiel mit Wasser. TU Berlin. Habilitation.

2005

37. Diehl, Dörte, Schaumann, Gabriele E. 2005. Zeitliche Änderung des Boden-Wasser-Kontaktwinkels im Verlaufe der Benetzung. Mitteilungen der Deutschen Bodenkundlichen Gesellschaft. 107 (1): 125-126.

36. Bayer, Julia V., Hurraß, Julia, Schaumann, Gabriele Ellen 2005. Influence of pH and drying conditions on the wettability of soil samples. Geophysical Research Abstracts. 7 (SSS8 Soil water repellency: origin, environme): EGU05-A-00416; SSS8-1FR5P-0147.

35. Schaumann, Gabriele Ellen, Hurraß, Julia, Bayer, Julia V., Diehl, Dörte, Hobley, Eleanor 2005. Wetting kinetics and water repellency in urban soils.

34. Diehl, Dörte, Schaumann, Gabriele Ellen 2005. Wetting kinetics determined from contact angle measurement. Geophysical Research Abstracts. 7 (SSS8 Soil water repellency: origin, environme): EGU05-A-00414; SSS8-1FR5P-0160.

33. Kirchner, Dörte, Braun, Burga, Rotard, Wolfgang, Szewzyk, Ulrich, Grohmann, Elisabeth, Schaumann, Gabriele Ellen 2005. Influence of biofilms on the hydrophobicity of urban soils. Geophysical Research Abstracts. 7 (SSS8 Soil water repellency: origin, environme): EGU05-A-03060; SSS8-1FR5P-0149.

32. Hurraß, Julia, Schaumann, Gabriele E. 2005. Sind Glasübergänge ein typisches Merkmal humoser Bodenproben?. Mitteilungen der Deutschen Bodenkundlichen Gesellschaft. 107 (2): 697-698.

2004

31. Hurraß, Julia, Schaumann, Gabriele Ellen 2004. Water repellency in Soils - a Consequence of SOM properties?. Eurosoil 2004. Freiburg, Germany: Inst. of Soil Science and Forest Nutrition, University of Freiburg. 127.

30. Schaumann, Gabriele Ellen 2004. The influence of water on physicochemical properties of soil organic matter. Crossing Borders- Molecular Mechanisms and Ecosystem processes. Proccedings of the 2nd Joint Annual meeting 2004. Aachen, Germany: Institut für Umweltforschung. 121.

29. Schaumann, Gabriele Ellen 2004. Hydration of Soil Organic Matter and Its Ecological Relevance. Eurosoil 2004. Freiburg, Germany: Inst. of Soil Science and Forest Nutrition, University of Freiburg. 185.

28. Schaumann, Gabriele Ellen 2004. Differential Scanning Kalorimetrie (DSC) und Protonenrelaxation (H-NMR Relaxation) zur Charakterisierung physikochemischer Prozesse im Boden.. Methodenworkshop Bodenbiologie - Bodenchemie - Bodenökologie. Witzenhausen, Germany: GfÖ and Deutsche Bodenkundliche Gesellschaft. 9.

27. Schaumann, G. E. 2004. Matrix relaxation and change of water state during hydration of peat. 3rd International Conference on Interfaces Against Pollutions. Julich, GERMANY: 163-170.

26. Rosenkranz, Stephan, Schaumann, Gabriele Ellen 2004. The influence of water content on the glass transition temperature in a peat soil. Crossing Borders- Molecular Mechanisms and Ecosystem processes. Proccedings of the 2nd Joint Annual meeting 2004. Aachen, Germany: Institut für Umweltforschung. 235.

25. Bayer, Julia V., Schaumann, Gabriele Ellen 2004. The influence of pH and drying conditions on the wettability of soil samples. Crossing Borders- Molecular Mechanisms and Ecosystem processes. Proccedings of the 2nd Joint Annual meeting 2004. Aachen, Germany: Institut für Umweltforschung. 223.

24. Schaumann, Gabriele Ellen, LeBoeuf, Eugene, J., Hurraß, Julia 2004. Interactions of water with wettable and hydrophobic soil surfaces: Types and effects of hydration. Interfaces against Pollution 2004. Jülich, Germany:

23. Schaumann, Gabriele E., LeBoeuf, Eugene J., Hurraß, Julia, Rosenkranz, Stephan, Rotard, Wolfgang 2004. Glass Transitions in swelling peat and soil samples. Proceedings of the 12th International meeting of the International Humic Substance Society. Sao Pedro - Sao Paulo - Brazil: accepted.

2003

22. Schaumann, Gabriele E., LeBoeuf, Eugene J. 2003. Glass Transitions in a Peat Soil: Influence of Water. Mitteilungen der Deutschen Bodenkundlichen Gesellschaft. 102 (1): 231-232.

21. Schaumann, Gabriele Ellen, LeBoeuf, Eugene J., Braun, Burga, Szewzyk, Ulrich, Rotard, Wolfgang 2003. Glass Transitions in Soil Samples and Biofilms?. Water and Organic Matter in Soils: Dynamics and Processes. Berlin: DFG, INTERURBAN. 84.

20. Hurraß, Julia, Schaumann, Gabriele Ellen, Hobley, Eleanor 2003. The kinetics of water uptake of hydrophobic and wettable soils. Kinetics of soil physico-chemical processes: the key to the environmental availability of pollutants and nutrients?. Berlin, Germany: Dept. Soil Science, Berlin University of Technology + German Soil Science Society. 24.

19. Schaumann, Gabriele Ellen, Hurraß, Julia, Stoffregen, Heiner, Müller, Martin, Rotard, Wolfgang, Hobley, Eleanor 2003. The kinetics of swelling of soil organic matter affect the pore size distribution in humic soil layers. Kinetics of soil physico-chemical processes: the key to the environmental availability of pollutants and nutrients?. Berlin, Germany: Dept. Soil Science, Berlin University of Technology + German Soil Science Society. 28.

18. Schaumann, Gabriele Ellen, Hurraß, Julia, Hobley, Eleanor, Rotard, Wolfgang 2003. Soil organic matter properties - the influence of the water status of soil samples. Water and Organic Matter in Soils: Dynamics and Processes. Berlin: DFG, INTERURBAN. 18.

17. Hurraß, Julia, Schaumann, Gabriele Ellen, Hobley, Eleanor, Rotard, Wolfgang 2003. Effects of soil moisture conditions on selected physico- chemical properties of soil extracts. Water and Organic Matter in Soils: Dynamics and Processes. Berlin: DFG, INTERURBAN. 74.

16. Hurraß, Julia, Schaumann, Gabriele Ellen, Hobley, Eleanor 2003. The kinetics of water uptake of hydrophobic and wettable soils (interurban). Water and Organic Matter in Soils: Dynamics and Processes. Berlin: DFG, INTERURBAN. 95.

15. Schaumann, Gabriele E., Hurraß, Julia 2003. Changes of porosity and soil physical chemistry due to drying and re-wetting cycles. Mitteilungen der Deutschen Bodenkundlichen Gesellschaft. 101 39-40.

14. Hurraß, Julia, Schaumann, Gabriele E. 2003. Wasseraufnahmeverhalten von hydrophoben und benetzbaren Bodenproben. Mitteilungen der Deutschen Bodenkundlichen Gesellschaft. 102 (1): 185-186.

13. Hurraß, Julia, Schaumann, Gabriele E. 2003. Phasenumwandlungen von Wasser unter veränderlichen Feuchtebedingungen. Mitteilungen der Deutschen Bodenkundlichen Gesellschaft. 101 31-32.

12. Schaumann, Gabriele Ellen, Müller, Martin, Hobley, Eleanor, Hurraß, Julia, Rotard, Wolfgang 2003. Are environmental processes affected by wetting and sewelling kinetics of soil organic matter?. Kinetics of soil physico-chemical processes: the key to the environmental availability of pollutants and nutrients?. Berlin, Germany: Dept. Soil Science, Berlin University of Technology + German Soil Science Society. 18.

11. Hurraß, Julia, Schaumann, Gabriele Ellen 2003. Phase transitions of water in soil subjected to varying moisture conditions. Water and Organic Matter in Soils: Dynamics and Processes. Berlin: DFG, INTERURBAN. 96.

10. Schaumann, Gabriele Ellen, Hurraß, Julia, Stoffregen, Heiner, Müller, Martin, Rotard, Wolfgang 2003. Swelling of soil organic matter and pore size distribution in Ah samples. Water and Organic Matter in Soils: Dynamics and Processes. Berlin: DFG, INTERURBAN. 97.

2002

9. Schaumann, Gabriele E., Hurraß, Julia, Berger, Susanne, Sieg, Karsten, Weber, Jan, Stoffregen, Heiner, Mueller, Martin, Rotard, Wolfgang 2002. Swelling of soil organic matter in humic soil samples: methods and relevance. Gabbour, Elham; Davies, G. 11th Conference of the International Humic Substance Society. Boston, MA (USA): 437-439.

8. Schaumann, Gabriele Ellen, Hurraß, Julia 2002. Phasenumwandlungen von Wasser unter veränderlichen Feuchtebedingungen. Dynamik physikalischer Bodeneigenschaften und die Auswirkung auf Wasserbewegung und Stofftransport. Hannover: Universität Hannover. 27.

7. Schaumann, Gabriele Ellen, Hurraß, Julia 2002. Changes of porosity and soil physical chemistry due to drying and re-wetting cycles. Dynamik physikalischer Bodeneigenschaften und die Auswirkung auf Wasserbewegung und Stofftransport. Hannover: Universität Hannover. 35.

6. Schaumann, Gabriele Ellen, Hobley, Eleanor, Hurraß, Julia, Rotard, Wolfgang 2002. Colloidal properties of DOM: Changes due to drying and remoistening Cycles?. Mitteilungen der Deutschen Bodenkundlichen Gesellschaft. 99 203-204.

5. Schaumann, Gabriele Ellen, Hobley, Eleanor, Hurraß, Julia 2002. Changes of colloidal properties of extracted DOM due to drying and re-wetting cycles. Mineral Surface and Colloid Chemistry in Soil and Aquatic Environments. Karlsruhe, Germany: ETH Zürich, Forschungszentrum Karlsruhe. 28.

2001

4. Schaumann, Gabriele Ellen, Hurraß, Julia 2001. 1H-NMR-Relaxation zur Untersuchung des Quellungszustandes der organischen Bodensubstanz? (1H-NMR-Relaxation: a method to investigate the state of swelling of soil organic matter?). Mitteilungen der Deutschen Bodenkundlichen Gesellschaft. 96 (1): 277-278.

3. Berger, Susanne, Sieg, Karsten, Weber, Jan, Schaumann, Gabriele Ellen, Rotard, Wolfgang, Kocher, Birgit, Wessolek, Gerd 2001. Extrahierbarkeit von PAK in Abhängigkeit von Wassergehalt und Befeuchtungsdauer (Extractibility of PAH as influenced by the water content and the hydration time). Mitteilungen der Deutschen Bodenkundlichen Gesellschaft. 96 (1): 151-152.

2000

2. Schaumann, Gabriele Ellen, Hurraß, Julia 2000. Water uptake and swelling behaviour of soil organic matter (SOM). Surface and Colloid Chemistry in the Soil and Aquatic Environments. Zürich, Switzerland: ETH Zürich. 32.

1. Schaumann, Gabriele Ellen, Hurraß, Julia 2000. Water uptake and swelling behaviour of soil organic matter (SOM). Mitteilungen der Deutschen Bodenkundlichen Gesellschaft. 92 25-28.

Theses

Identifizierung und Charakterisierung amphiphiler grenzflächenaktiver Substanzen aus Bodenproben unterschiedlicher Benetzbarkeit
Diploma: Langbein, J. (2007), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and D. Diehl

 The influence of amphiphilic substances on water repellency of effluent irrigated soils
Project: Görnitz, M. (2006), TU Berlin / Volcani Center, Rehovot, Israel-Environmental Chemistry. Adv: G. E. Schaumann and E. Graber

 Untersuchung des Biofilmwachstums auf Aufwuchsmaterialien unterschiedlicher Textur
Diploma: Korn, H. (2006), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and E. Grohmann

 Screening von Bakterienisolaten aus urbanen Böden auf Wachsabbau sowie phylogenetische Charaktersierung der Bakterien durch 16S rDNA Sequenzierung.
Project: Dunkelberg, E. (2005), TU Berlin-Environmental Microbiology. Adv: E. Grohmann and G. E. Schaumann

 Einfluss von Biofilmen hydrophober und hydrophiler Bakterienisolate aus urbanen Standorten auf die Benetzbarkeit von Bodenproben
Diploma: Kirchner, D. (2005), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and E. Grohmann

 Physikalische, chemische und biologische Einflussfaktoren für die Hydrophobizität auf urbanen Standorten (Physical, chemical and biological factors of influence for water repellency on urban sites)
Diploma: Bayer, J. V. (2004), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and E. Grohmann

 Literaturstudie zu den Einflussfaktoren für die Hydrophobie in Böden
Diploma: Hapka, A. (2004), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and W. Rotard

 Freisetzungskinetik organischer Substanzen aus hydrophoben und benetzbaren Proben urbaner Standorte
Diploma: Hobley, E. (2004), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann

 Thermische und rheologische Eigenschaften von Biofilmen urbaner Mikroorganismengesellschaften aus Festbettreaktoren
Diploma: Klaucke, F. (2004), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann, E. Grohmann and W. Rotard

 Bedeutung der Austrocknung und Wiederbefeuchtung für die Wasseraufnahme von Bodenproben und die Eigenschaften wasserextrahierbarer Substanzen
Project: Hobley, E. (2003), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and W. Rotard

Interactios between Soil Organic Matter and Water with special respect to the Glass Transition Behavior
PhD: Hurraß, J. (2006), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and W. Rotard

 Influence of multivalent cations on glass transitions in precipitated dissolved organic matter
Diploma: Frank, J. (2005), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and F. Lang

 Bleibindung in Waldbodenproben und ihre Beeinflussung durch die Vernetzung der organischen Bodensubstanz
Project: Rudolph, N. (2005), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann

 Literaturstudie zu den Einflussfaktoren für die Hydrophobie in Böden
Diploma: Hapka, A. (2004), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and W. Rotard

 Freisetzungskinetik organischer Substanzen aus hydrophoben und benetzbaren Proben urbaner Standorte
Diploma: Hobley, E. (2004), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann

 Einfluss von Wasser und Quervernetzung durch Kationen auf makromolekulare Eigenschaften von Torf
Diploma: Rosenkranz, S. (2004), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and W. Rotard

 Bedeutung der Austrocknung und Wiederbefeuchtung für die Wasseraufnahme von Bodenproben und die Eigenschaften wasserextrahierbarer Substanzen
Project: Hobley, E. (2003), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and W. Rotard

 Einfluss von Mikroorganismen auf 1H-NMR-Messungen bei Wasseraufnahmeprozessen von Böden
Project: Jaeger, F. (2003), TU Berlin-Environmental Chemistry. Adv: G. E. Schaumann and W. Rotard

Staff

Phase I

Dipl.-Ing. Dörte Diehl (Scientific Assistant)
Dipl.-Biol. Burga Braun (Scientific Assistant)
Dr. Julia Hurraß (Scientific Assistant)
Niels Meyer (Student Assistant)
Julia Bayer (Student Assistant)
Stephan Bowe (Student Assistant)
Jennifer Frank (Student Assistant)
Jeannette Regnery (Technical Assistant)
Katharina Knobel (Technical Assistant)
Claudia Stoltz (Technical Assistant)

Phase II

Dr. Julia Hurraß (Scientific Assistant)
Janet Babatz (Student Assistant)
Fabian Jaeger (Student Assistant)
Eleanor Hobley (Student Assistant)
Julia Bayer (Student Assistant)
Jeannette Regnery (Technical Assistant)
Katharina Knobel (Technical Assistant)

Collaborations

- Prof. Dr. Eugene J. LeBoeuf, Vanderbilt University, Nashville, Tennessee, USA
- Prof. Dr. Gerd Wessolek, Dr. Heiner Stoffregen, TU Berlin, Dept. Soil Protection
- Prof. Dr. U. Yaramanci, Dr. Martin Müller, TU Berlin, Dept. Geophysics
- Prof. Dr. U. Szewzyk, PD Dr. Elisabeth Grohmann, Dr. Uta Boeckelmann,
TU Berlin, Dept. Environmental Microbiology
- PD Dr. Thorsten Reemtsma, Prof. Dr. Martin Jekel, TU Berlin, Dept. of Water Quality Control
- Prof. Dr. G. Weigmann, Dr. Silvia Pieper, FU Berlin, Dept. Zoology

zuletzt verändert: 08.10.2012 14:43

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